Transition Metal Arene p-Complexes in Organic Synthesis and Catalysis (Topics in Organometallic Chemistry) [Englisch] [Gebundene Ausgabe]

"The editor has succeeded well inside collection of authors, who've particularly strong profiles in their respective regions of research."……"Overall, this really is a fantastic book having a great deal of valuable, concisely presented information. The literature references usually end using the year 2001. Occasional language shortcomings, or formulas which are printed too small, cannot significantly detract in the high quality in the contributions." Holger Butenschön, Institute for Organic Chemistry, University of Hannover Journal: Angewandte Chemie, Vol. 44, Issue 11, p. 1591-1592 (2005)

Metal-arene pi-complexes show a rich and varied chemistry. The metal adds another dimension to the planar aromatic compounds and coordination of an metal to a arene thus not only altering the reactivity of ring-carbons and substituents but additionally makes possible reactions that cause chiral non-racemic products. This book, organized in nine chapters and written by leading scientists inside the field provides the reader having an up-to-date treatise about the subject organized as outlined by reaction type and use. It covers the wide spectrum of arene activation: in the electrophilic activation of h6-bound arene by pi-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated arene complexes. The preparation of complexes is detailed, as include the scope, limitations and challenges of reactions in contemporary pi-arene metal chemistry with special attention provided to asymmetric transformations. The emphasis of the book is on transformations of great interest to organic synthesis and about the use in the complexes as catalysts or as chiral ligands. The book is written for academic and industrial researchers in organic, organometallic, and inorganic chemistry also as for advanced chemistry students.



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